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Lead Free Processing - Process Equipment Issues
BY S S Kwa, Speedline Technologies Asia

Overview

  • Impact of SMT process equipment is a function of selected solder paste
    • Paste Technology
    • Reflow temperature
    • Flux activity
  • In general equipment is capable and compatible
  • This presentation examines each SMT process step with a view to the impact of no lead materials
The Screen Printing Process
  • Matching performance with new powder and flux formulations is as any solder paste.
  • For the printing process the lead free alternatives' factors of impact are similar to 63Sn/37Pb:
    • Stencil life
    • Environmental conditions(temperature and humidity)
    • Response to pause
    • Squeegee Speed
    • Stencil wiping frequency
    • Compatibility with pump head and other pump head technologies

The Component Placement Process

  • For the placing process the lead free alternatives' factors of impact are similar to Sn/Pb:
    • Tack (the ability of the solder paste to hold any particular component in position before the solder paste is reflowed)
    • Environmental conditions (temperature and humidity)

Thermal Energy Transfer Comparison

  • Radiant (IR) heat transfer: Temperature differential between source and target is 4x the setpoint.
  • Forced convection heat transfer: Temperature differential between source and target is directly proportional.

Effect of Convection on Profiles

  • More energy is transferred to the product
  • Minimal shadowing effect
  • Lower heating element temperatures
  • Setpoint = board temperature
  • Soaking without overheating smaller components
  • Small δT between small and big components

Effect of Nitrogen on Profile

  • Nitrogen is thermally invisible to the profile
  • Convection blowers deliver heat transfer the same in oxygen as in nitrogen
  • Nitrogen affects wetting and finish not temperature

Effect of N2 on Solder Joints

  • Higher wetting forces when no air is present resulting in shorter wetting time
  • No re-oxidation in the oven with nitrogen
  • Beneficial for OSP's where the coating volatilizes and breaks down at temp
  • Best used with no clean fluxes
  • Benefits fine pitch for bridging
  • Enhanced cosmetics
    • Bright, shiny solder joints
    • No laminate discoloration

Reflow

  • Thermal management
  • Flux recovery
  • Equipment reliability

The Reflow Soldering Process

  • Greatest impact of all the process
  • All currentlu preferred no lead solder pastes reflow at higher temperatures (Peak: 215°C) than leaded solder pastes
    • 63/37 reflow takes >45 seconds time above liquidous with a peak 215~220°C (Melting point 183°C)
  • Ovens with higher temperatures capabilities may be needed
  • Ovens with high mass profile capabilities may be needed
  • Due to the nature of the condensate material produces during the reflow process it may be necessary to use a flux management system (active intermal exhaust) to remove the residue - minimizing the oven cleaning requirements

Wave Soldering Process

  • Thermal management
  • Dross control
  • Inert atmosphere - retrofit?
  • Flux
  • Corrosion of stainless steel - may require a retrofit kit.
    • Tin, at elevated temperatures is corrosive to the stainless steel.
      • MELONITE™ treatment
      • Grey cast iron with Chromium as an additive.
  • The introduction of no lead solder will have some level of impact on the wave soldering process and wave soldering equipment:
    • Most common no lead material is 99.3%Sn/0.7%Cu & 96.5%Sn/3.5%Ag may need to be processed at a higher temperature than leaded solders affecting:
      • Solder pot materials of construction
      • Pre heat considerations (Thermal shock)
    • Alloy wetting
  • Cost implications
    • Nitrogen soldering
    • Additional heat costs money
    • Equipment life cycle of current equipment

Inspection

  • Lead-free solders do not wet as well as traditional solders
  • Many lead-free alloys yield a duller surface finish (i.e. less shiny joints)
  • Pass/fail criteria may need to be reviewed

Cleaning

  • Baked-on fluxes, higher temperature reflow profiles aggregate the cleaning process of "no cleans" materials
    • Many users still clean no-clean materials
      • Improve conformal coating adhession
      • Improve casmetics
      • Meet customer specifications

Process Impact Overview

  • No "drop-in" lead free process available
  • There may be some equipment considerations in the reflow, wave solder cleaning and inspection processes.
  • Definite impact of higher processing temperatures on soldering materials, boards, components and subassemblies.

(10/30/2000)


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